The story
Know comes from Old English cnāwan, "to know, perceive, recognize". The root is very old and widely shared: Latin (co)gnōscere (the source of recognize and cognition) and Greek gnōsis, "knowledge", come from the same ancestor. Notice the pattern — a G or K sound before the N in all of them.
English kept that K for centuries. Old and Middle English speakers said it, and so a word like knowledge began with a real "k-n". In the 1600s, educated speech simplified the kn- cluster to plain N, the same change that silenced knee, knife and knight.
The spelling had been fixed long before, so the K stayed. It still earns its keep in one way: it separates know from no, and knew from new — pairs that sound identical but are spelled differently.
